Transport in Porous Media

, Volume 61, Issue 1, pp 93–107

Role of pH in Electro-Osmosis: Experimental Study on NaCl–Water Saturated Kaolinite

  • Karim Beddiar
  • Teddy Fen-Chong
  • André Dupas
  • Yves Berthaud
  • Patrick Dangla
Article

DOI: 10.1007/s11242-004-6798-9

Cite this article as:
Beddiar, K., Fen-Chong, T., Dupas, A. et al. Transp Porous Med (2005) 61: 93. doi:10.1007/s11242-004-6798-9

Abstract

Electro-osmosis experiments were conducted on rigid cylindrical samples containing 0.01 M NaCl–water saturated Speswhite kaolinite. It is experimentally found that the electro-osmotic permeability is pH-dependent. It is also experimentally found that time and spatial variations of the sample pH and of the pore water pressure correlate. This is qualitatively confirmed by a simple analysis that couples the electro-osmotic and hydraulic flows through the pH-dependent electro-osmotic permeability. However quantitative agreement between the experimental and numerical values of the pore water pressure is not obtained throughout the whole sample. This suggests that the hydraulic permeability may also depend on the pH.

Keywords

electro-osmosiselectrokineticphysico-chemical couplingspore pressurepHkaolinitehydraulic permeabilityelectro-osmotic permeability

Copyright information

© Springer 2005

Authors and Affiliations

  • Karim Beddiar
    • 1
    • 2
  • Teddy Fen-Chong
    • 1
  • André Dupas
    • 1
    • 3
  • Yves Berthaud
    • 1
    • 4
  • Patrick Dangla
    • 1
  1. 1.Institut NavierLMSGCChamps-sur-MarneFrance
  2. 2.École d’Ingénieurs du CESICentre de BagneuxBagneuxFrance
  3. 3.Institut NavierLAMIMarne-la-ValléeFrance
  4. 4.LMT (UMR 8535 ENS Cachan/Université Paris VI/CNRS) 61 avenue Président WilsonCachanFrance