Russian Chemical Bulletin

, Volume 62, Issue 3, pp 657–660

Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts

  • V. V. Ermolaev
  • D. M. Arkhipova
  • L. Sh. Nigmatullina
  • I. Kh. Rizvanov
  • V. A. Milyukov
  • O. G. Sinyashin
Full Articles

DOI: 10.1007/s11172-013-0088-z

Cite this article as:
Ermolaev, V.V., Arkhipova, D.M., Nigmatullina, L.S. et al. Russ Chem Bull (2013) 62: 657. doi:10.1007/s11172-013-0088-z

Abstract

Palladium nanoparticles with an average size of 2.5±0.5 nm formed from palladium acetate in the presence of tri-tert-butyl(decyl)phosphonium tetrafluoroborate without an additional reducing agent exhibit high activity as a catalyst for the Suzuki cross-coupling reaction involving bromo- and chloroarenes under mild conditions.

Key words

palladium nanoparticlesbromoarenescatalysiscross-couplingarylboronic acids

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • V. V. Ermolaev
    • 1
  • D. M. Arkhipova
    • 1
  • L. Sh. Nigmatullina
    • 1
  • I. Kh. Rizvanov
    • 1
  • V. A. Milyukov
    • 1
  • O. G. Sinyashin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research CenterRussian Academy of SciencesKazanRussian Federation