Russian Chemical Bulletin

, Volume 56, Issue 11, pp 2284–2289

Synthesis and structures of new conformationally rigid 1-aza-1,3-dienes of the acenaphthene series

  • A. A. Skatova
  • I. L. Fedushkin
  • O. V. Maslova
  • M. Hummert
  • H. Schumann
Article

DOI: 10.1007/s11172-007-0360-1

Cite this article as:
Skatova, A.A., Fedushkin, I.L., Maslova, O.V. et al. Russ Chem Bull (2007) 56: 2284. doi:10.1007/s11172-007-0360-1

Abstract

The Wittig reaction of 1-tert-butyliminoacenaphthen-2-one with benzylidenetriphenylphosphoranes produces new 1-aza-1,3-dienes of the acenaphthene series, which can bind butyllithium to the C=C bond of the enimine fragment C=C-C=N.

Key words

ketiminesimino ketoneseniminesphosphorus ylidesWittig reactionX-ray diffraction studyacenaphthenes

Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • A. A. Skatova
    • 1
  • I. L. Fedushkin
    • 1
  • O. V. Maslova
    • 1
  • M. Hummert
    • 2
  • H. Schumann
    • 2
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii NovgorodRussian Federation
  2. 2.Institute of ChemistryTechnical University of BerlinBerlinGermany