Russian Chemical Bulletin

, Volume 55, Issue 5, pp 821–827

Anionic chiral cobalt(III) complexes as catalysts of asymmetric synthesis of cyanohydrins

  • Yu. N. Belokon’
  • V. I. Maleev
  • I. L. Mal’fanov
  • T. F. Savel’eva
  • N. S. Ikonnikov
  • A. G. Bulychev
  • D. L. Usanov
  • D. A. Kataev
  • M. North
Article

DOI: 10.1007/s11172-006-0338-4

Cite this article as:
Belokon’, Y.N., Maleev, V.I., Mal’fanov, I.L. et al. Russ Chem Bull (2006) 55: 821. doi:10.1007/s11172-006-0338-4

Abstract

Chiral coordinatively saturated cobalt(III) complexes with Schiff bases of enantio-pure amino acids are formed as Λ and Δ-isomers, which are not transformed into each other under normal conditions. These complexes catalyze the formation of enantiomerically enriched cyanohydrins from aldehydes and Me3SiCN under homo-and heterogeneous catalysis.

Key words

enantioselective phase transfer catalysischiral cobalt(III) complexescyanohydrinsaldehydestrimethylsilyl cyanideamino acidssalens

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Yu. N. Belokon’
    • 1
  • V. I. Maleev
    • 1
  • I. L. Mal’fanov
    • 2
  • T. F. Savel’eva
    • 1
  • N. S. Ikonnikov
    • 1
  • A. G. Bulychev
    • 2
  • D. L. Usanov
    • 3
  • D. A. Kataev
    • 3
  • M. North
    • 4
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryKaliningrad State UniversityKaliningradRussian Federation
  3. 3.Higher Chemical CollegeRussian Academy of SciencesMoscowRussian Federation
  4. 4.School of Natural Sciences, Bedson BuildingUniversity of Newcastle upon TyneNewcastle upon TyneUK