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Mild preparation of chromeno[2,3-d]pyrimidines catalyzed by Brønsted acidic ionic liquids under solvent-free and ambient conditions

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Abstract

Brønsted acidic ionic liquids, namely 2-pyrrolidonium hydrogensulfate, N-methyl-2-pyrrolidonium hydrogensulfate, N-methyl-2-pyrrolidonium dihydrogenphosphate, (4-sulfobutyl)tris(4-sulfophenyl)phosphonium hydrogensulfate, triphenyl(propyl-3-sulfonyl)phosphonium toluenesulfonate, l-prolinium sulfate, and l-prolinium nitrate, catalyzed efficient one-pot pseudo-four-component reaction of salicylaldehydes, malononitrile, and secondary amine for preparation of chromeno[2,3-d]pyrimidines under solvent-free conditions at room temperature. The catalysts show environmentally benign character and can be easily prepared, stored, and recovered without obvious significant loss of activity.

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Scheme 1
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Acknowledgments

We are grateful to the University of Sistan and Baluchestan Research Council for partial support of this research.

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Correspondence to Hamid Reza Shaterian.

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Shaterian, H.R., Aghakhanizadeh, M. Mild preparation of chromeno[2,3-d]pyrimidines catalyzed by Brønsted acidic ionic liquids under solvent-free and ambient conditions. Res Chem Intermed 39, 3877–3885 (2013). https://doi.org/10.1007/s11164-012-0889-y

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  • DOI: https://doi.org/10.1007/s11164-012-0889-y

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