Reaction Kinetics and Catalysis Letters

, Volume 90, Issue 2, pp 323–329

Detailed balance in reaction kinetics — Consequence of mass conservation?

Article

DOI: 10.1007/s11144-007-4996-5

Cite this article as:
Pekař, M. React Kinet Catal Lett (2007) 90: 323. doi:10.1007/s11144-007-4996-5

Abstract

Detailed balance condition for triangular isomerisation mechanism is derived from the more general permanence of atoms, consequently, it should be viewed as a special equilibrium result of mass conservation.

Keywords

Detailed balance kinetics and thermodynamics mechanism 

Copyright information

© Akadémiai Kiadó 2007

Authors and Affiliations

  1. 1.Institute of Physical and Applied Chemistry, Faculty of ChemistryBrno University of TechnologyBrnoCzech Republic

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