Deep metastable eutectic nanometer-scale particles in the MgO–Al2O3–SiO2 system
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- Rietmeijer, F.J.M. & Nuth, J.A. J Nanopart Res (2011) 13: 3149. doi:10.1007/s11051-010-0210-1
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Laboratory vapor phase condensation experiments systematically yield amorphous, homogeneous, nanoparticles with unique deep metastable eutectic compositions. They formed during the nucleation stage in rapidly cooling vapor systems. These nanoparticles evidence the complexity of the nucleation stage. Similar complex behavior may occur during the nucleation stage in quenched-melt laboratory experiments. Because of the bulk size of the quenched system many of such deep metastable eutectic nanodomains will anneal and adjust to local equilibrium but some will persist metastably depending on the time–temperature regime and melt/glass transformation.