Journal of Thermal Analysis and Calorimetry

, Volume 95, Issue 2, pp 437–444

Synthesis, molecular structure, non-isothermal decomposition kinetics and adiabatic time to explosion of 3,3-dinitroazetidinium 3,5-dinitrosalicylate

  • H. X. Ma
  • B. Yan
  • Z. N. Li
  • J. R. Song
  • R. Z. Hu
Article

DOI: 10.1007/s10973-008-9255-0

Cite this article as:
Ma, H.X., Yan, B., Li, Z.N. et al. J Therm Anal Calorim (2009) 95: 437. doi:10.1007/s10973-008-9255-0

Abstract

The title compound 3,3-dinitroazetidinium (DNAZ) 3,5-dinitrosalicylate (3,5-DNSA) was prepared and the crystal structure has been determined by a four-circle X-ray diffractometer. The thermal behavior of the title compound was studied under a non-isothermal condition by DSC and TG/DTG techniques. The kinetic parameters were obtained from analysis of the TG curves by Kissinger method, Ozawa method, the differential method and the integral method. The kinetic model function in differential form and the value of Ea and A of the decomposition reaction of the title compound are f(α)=4α3/4, 130.83 kJ mol−1 and 1013.80s−1, respectively. The critical temperature of thermal explosion of the title compound is 147.55 °C. The values of ΔS, ΔH and ΔG of this reaction are −1.35 J mol−1 K−1, 122.42 and 122.97 kJ mol−1, respectively. The specific heat capacity of the title compound was determined with a continuous Cp mode of mircocalorimeter. Using the relationship between Cp and T and the thermal decomposition parameters, the time of the thermal decomposition from initiation to thermal explosion (adiabatic time-to-explosion) was obtained.

Keywords

adiabatic time to explosion3,3-dinitroazetidinium 3,5-dinitrosalicylate (DNAZ)·(3,5-DNSA)kineticsmolecular structurespecific heat capacity

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2009

Authors and Affiliations

  • H. X. Ma
    • 1
  • B. Yan
    • 1
  • Z. N. Li
    • 1
  • J. R. Song
    • 1
    • 2
  • R. Z. Hu
    • 3
  1. 1.College of Chemical Engineering, Shaanxi Key Laboratory of Physico-Inorganic ChemistryNorthwest UniversityXi’anChina
  2. 2.Conservation Technology DepartmentThe Palace MuseumBeijingChina
  3. 3.Xi’an Modern Chemistry Research InstituteXi’anChina