Journal of Thermal Analysis and Calorimetry

, Volume 80, Issue 2, pp 317–321

Study on volumetric measurement and correlations for MTBE+1-propanol+decane at 298.15 K and atmospheric pressure

  • M. M. Mato
  • S. M. Cebreiro
  • P. V. Verdes
  • A. V. Pallas
  • J. L. Legido
  • M. I. Paz Andrade
Article

DOI: 10.1007/s10973-005-0653-2

Cite this article as:
Mato, M., Cebreiro, S., Verdes, P. et al. J Therm Anal Calorim (2005) 80: 317. doi:10.1007/s10973-005-0653-2

Summary

Experimental densities for the ternary mixture x1MTBE+x21-propanol+(1-x1-x2)decane and the binary mixtures xMTBE +(1-x)1-propanol and x1-propanol+(1-x)decane have been measured at 298.15 K and atmospheric pressure, using a DMA 4500 Anton Paar densimeter. Excess molar volumes were determined from the densities of the pure liquids and mixtures. Attending to the symmetry of the studied mixtures, suitable fitting equations have been used in order to correlate adequately the experimental data. For the ternary mixture, experimental data were also used to test several empirical expressions for estimating ternary properties from experimental binary results.

binary mixtures ternary mixture excess molar volumes empirical expressions 1-propanol tert-butyl methyl ether (MTBE) decane 

Copyright information

© Springer-Verlag/Akadémiai Kiadó 2005

Authors and Affiliations

  • M. M. Mato
    • 1
  • S. M. Cebreiro
    • 2
  • P. V. Verdes
    • 3
  • A. V. Pallas
    • 4
  • J. L. Legido
    • 5
  • M. I. Paz Andrade
    • 6
  1. 1.Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo
  2. 2.Departamento de Física Aplicada, Facultad de Físicas, Campus Universitario Sur, Universidade de Santiago de Compostela
  3. 3.Departamento de Física Aplicada, Facultad de Físicas, Campus Universitario Sur, Universidade de Santiago de Compostela
  4. 4.Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo
  5. 5.Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo
  6. 6.Departamento de Física Aplicada, Facultad de Físicas, Campus Universitario Sur, Universidade de Santiago de Compostela

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