Journal of Solution Chemistry

, Volume 41, Issue 1, pp 130–142

Dissociation Constants of Protonated Amines in Water at Temperatures from 293.15 K to 343.15 K

Authors

  • M. R. Simond
    • Laboratoire de Thermodynamique et Interactions MoléculairesClermont Université, Université Blaise Pascal
    • Laboratoire de Thermodynamique et Interactions Moléculaires, CNRSUMR 6272
    • Laboratoire de Thermodynamique et Interactions MoléculairesClermont Université, Université Blaise Pascal
    • Laboratoire de Thermodynamique et Interactions Moléculaires, CNRSUMR 6272
  • Y. Coulier
    • Laboratoire de Thermodynamique et Interactions MoléculairesClermont Université, Université Blaise Pascal
    • Laboratoire de Thermodynamique et Interactions Moléculaires, CNRSUMR 6272
  • L. Rodier
    • Laboratoire de Thermodynamique et Interactions MoléculairesClermont Université, Université Blaise Pascal
    • Laboratoire de Thermodynamique et Interactions Moléculaires, CNRSUMR 6272
  • J.-Y. Coxam
    • Laboratoire de Thermodynamique et Interactions MoléculairesClermont Université, Université Blaise Pascal
    • Laboratoire de Thermodynamique et Interactions Moléculaires, CNRSUMR 6272
Article

DOI: 10.1007/s10953-011-9790-3

Cite this article as:
Simond, M.R., Ballerat-Busserolles, K., Coulier, Y. et al. J Solution Chem (2012) 41: 130. doi:10.1007/s10953-011-9790-3

Abstract

The dissociation constants of protonated 2-amino-1-ethanol (MEA), diethanol amine (DEA), triethanol amine (TEA), methyldiethanol amine (MDEA), 2-amino-2-methyl-1-propanol (AMP), 3-dimethylamino-1-propanol (DMAP), tris(hydromethyl)aminomethane (THAM), 2-[2-(dimethylamino)ethoxy]ethanol (DMAEOE) and, 1,2-bis(2-aminoethoxy)ethane (DiAEOE) were determined in the temperature range 293.15 to 343.15 K using a potentiometric titration method. The experimental technique was first validated using as reference the available literature data of MDEA. The dissociation enthalpies of amines were derived from their dissociation constants using the Van’t Hoff equation. Experimental dissociation constants and dissociation enthalpies were discussed in term of amine structure and compared with literature values when available.

Keywords

Alkanolamine Ethoxyamine Dissociation constant Dissociation enthalpy Potentiometry

Abbreviations

Symbols

K

dissociation constant

Δd H

standard enthalpies of dissociation

ρ w

volumic mass of pure water

A,B,C

adjustable parameters for Eq. 8

a

activity

γ

activity coefficient

m

molality

c

molarity

n

mole number

n 0

initial mole number

z

charge number

k

ionic radius parameter

T

temperature

A D,B D

Debye–Hückel constants

I

ionic strength

σ,s

standard deviation

Subscripts

Am

amine

AmH+

protonated amine

H+

hydrogen ion

OH

hydroxide ion

Cl

chloride ion

w

water

Copyright information

© Springer Science+Business Media, LLC 2012