Dielectric Constants of Water, Methanol, Ethanol, Butanol and Acetone: Measurement and Computational Study
First Online: 26 May 2010 Received: 10 June 2009 Accepted: 08 December 2009 DOI:
10.1007/s10953-010-9538-5 Cite this article as: Mohsen-Nia, M., Amiri, H. & Jazi, B. J Solution Chem (2010) 39: 701. doi:10.1007/s10953-010-9538-5 Abstract
The dielectric constants (relative permittivities) of water, methanol, ethanol, butanol and acetone were measured at 91.3 kPa and (283.15 and 293.15) K and are reported here. The dielectric constants were determined by using a new setup based on a low-pass filter. The obtained dielectric constant values are compared with those reported in the literature, and are consistent with those reported in the literature. The obtained dielectric constant data were also compared with those calculated by the Kirkwood model. The comparisons indicated that Kirkwood model can be successfully used for calculation of dielectric constants of the pure fluids.
Keywords Dielectric constant Low-pass-filter Capacitor Kirkwood model References
Jennings, S.G.: A method of measurement of the dielectric constant of some liquids. Phys. Educ.
, 40–42 (1977)
Fernandez, D.P., Goodwin, A.R.H., Levelt Sengers, J.M.H.: Measurements of the relative permittivity of liquid water at frequencies in the range of 0.1 to 10 kHz and at temperatures between 273.1 and 373.2 K at ambient. Int. J. Thermophys.
, 929–955 (1995)
Goodwin, R.H., Mehl, J.B., Moldover, M.R.: Reentrant radio-frequency resonator for automated phase-equilibria and dielectric measurements in fluids. Rev. Sci. Instrum.
, 4294–4298 (1996)
Kaatze, U.: The dielectric properties of water in its different states of interaction. J. Solution Chem.
, 1049–1112 (1997)
Anderson, G.S., Miler, R.C., Goodwin, R.H.: Static dielectric constants for liquid water from 300 K to 350 K at pressure to MPa using a new radio-frequency resonator. J. Chem. Eng. Data
, 549–554 (2000)
Buckley, F., Maryott, A.A.: Tables of dielectric dispersion data for pure liquids and dilute solutions. NBS Circular No. 589, National Bureau of Standards, Washington, DC (1958)
Dunn, L.A., Stokes, R.H.: Pressure and temperature dependence of the electrical permittivities of formamide and water. Trans. Faraday Soc.
, 2906–2912 (1996)
Åkerlöf, G.: Dielectric constants of some organic solvent-water mixtures at various temperatures. J. Am. Chem. Soc.
, 4125–4139 (1932)
Archer, D.G., Wang, P.: The dielectric constant of water and Debye–Hückel limiting law slopes. J. Phys. Chem. Ref. Data
, 371–411 (1990)
Owen, B.B., Miller, R.C., Milner, C.E., Cogan, H.L.: The dielectric constant of water as a function of temperature and pressure. J. Phys. Chem.
, 2065–2070 (1961)
Dannhauser, W., Bahe, L.W.: Dielectric constant of hydrogen bonded liquids. III. Superheated alcohols. J. Chem. Phys.
, 3058–3066 (1964)
Floriano, W.B., Nascimento, M.A.C.: Dielectric constant and density of water as a function of pressure at constant temperature. Braz. J. Phys.
, 38–41 (2004)
Hamelin, J., Mehl, J.B., Moldover, M.R.: The static dielectric constant of liquid water between 274 and 418 K near the saturated vapor pressure. Int. J. Thermophys.
, 1359–1380 (1998)
Hamelin, J., Mehl, J.B., Moldover, M.R.: Resonators for accurate dielectric measurements in conducting liquids. Rev. Sci. Instrum.
, 255–260 (1998)
Marcus, Y., Hefter, G.: On the pressure and electric field dependencies of the relative permittivity of liquids. J. Solution Chem.
, 575–592 (1999)
Sivasubramanian, S., Widom, A., Srivastava, Y.N.: The Clausius–Mossotti phase transition in polar liquids. Physica A
, 356–366 (2005)
Wang, P., Anderko, A.: Computation of dielectric constants of solvent mixtures and electrolyte solutions. Fluid Phase Equil.
, 103–122 (2001)
Hasted, J.B., Ritson, D.M., Collie, C.H.: Dielectric properties of aqueous ionic solutions. Parts I and II. J. Chem. Phys.
, 1–21 (1948)
Akhadov, Y.Y.: Dielectric Properties of Binary Solutions. Pergamon, New York (1980)
Lowery, T.H., Richardson, K.S.: Mechanism and Theory in Organic Chemistry, 3d edn. Harper Collins Publishers, New York (1987)
Tanford, C.: The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd edn. Wiley, New York (1973)
Taylor, J.T., Huang, Q. (eds.): CRC Handbook of Electrical Filters. CRC Press, Boca Raton (1997)
Garland, C.W., Niber, J.W., Shomaker, D.: Experiment in Physical Chemistry, 7th edn. McGraw-Hill, Boston (2003)
Gregory, A.P., Clarke, R.N.: Traceable measurements of the static permittivity of dielectric reference liquids over the temperature range 5–50°C. Meas. Sci. Technol.
, 1506–1516 (2005)
Lide, D.R.: Handbook of Chemistry and Physics, 85th edn. CRC Press, Boca Raton (2004)
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