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para-Selectivity of silicalite-1 coated MFI type galloaluminosilicate in aromatization of light alkanes

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Abstract

MFI type galloaluminosilicates (GaAlMFI) were coated with inert silicalite-1 layers. The silicalite-1 coating could improve the para-selectivity for xylene production in aromatization of propane. In the silicalite-1 coating step, low alkali concentration in the synthesis solution enhanced para-selectivity. A proton-exchange procedure also had an impact on the para-selectivity. Significant decrease of para-selectivity was observed over the silicalite-1 coated GaAlMFI with repeated proton-exchange. From the 71Ga and 27Al MAS NMR measurements, demetalation occurred during the proton-exchange process, and those metal species is likely to become catalytically active sites without para-selectivity. From the aromatization of propane and n-butane, para-selectivity in n-butane aromatization was found to be higher than that in propane aromatization. From the product distribution, naphthalene and its derivatives were easier to be produced in propane aromatization compared to n-butane aromatization. The formation of naphthalene and its derivatives may relate to decrease in the para-selectivity in propane aromatization.

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References

  1. J. Wei, J. Catal. 76, 433 (1982)

    Article  CAS  Google Scholar 

  2. Y.S. Bhat, J. Das, K.V. Rao, A.B. Halgeri, J. Catal. 159, 368 (1996)

    Article  CAS  Google Scholar 

  3. J.H. Kim, T. Kunieda, M. Niwa, J. Catal. 173, 433 (1998)

    Article  CAS  Google Scholar 

  4. Z. Lai, G. Bonilla, I. Diaz, J.G. Nery, K. Sujaoti, M.A. Amat, E. Kokkoli, O. Terasaki, R.W. Thompson, M. Tsapatsis, D.G. Vlachos, Science 300, 456 (2003)

    CAS  Google Scholar 

  5. N.Y. Chen, W.W. Kaeding, F.G. Dwyer, J. Am. Chem. Soc. 101, 6783 (2003)

    Article  Google Scholar 

  6. W.W. Kaeding, C. Chu, L.B. Young, B. Weinstein, S.A. Butter, J. Catal. 67, 159 (1981)

    Article  CAS  Google Scholar 

  7. M. Niwa, M. Kato, T. Hattori, Y. Murakami, J. Phys. Chem. 90, 6233 (1986)

    Article  CAS  Google Scholar 

  8. J.H. Kim, A. Ishida, M. Okajima, M. Niwa, J. Catal. 161, 387 (1996)

    Article  CAS  Google Scholar 

  9. Y.H. Yue, Y. Tang, Y. Liu, Z. Gao, Ind. Eng. Chem. Res. 35, 430 (1996)

    Article  CAS  Google Scholar 

  10. D. Lu, J.N. Kondo, K. Domen, H.A. Begum, M. Niwa, J. Phys. Chem. B 108, 2295 (2004)

    Article  CAS  Google Scholar 

  11. J.A. Biscardi, E. Iglesia, Catal. Today 31, 207 (1996)

    Article  CAS  Google Scholar 

  12. J.A. Biscardi, G.D. Meitzner, E. Iglesia, J. Catal. 179, 192 (1998)

    Article  CAS  Google Scholar 

  13. J. Heemsoth, E. Tegeler, F. Roessner, A. Hagen, Microporous Mesoporous Mater. 46, 185 (2001)

    Article  CAS  Google Scholar 

  14. L.M. Lubango, M.S. Scurrell, Appl. Catal. A Gen. 235, 265 (2002)

    Article  CAS  Google Scholar 

  15. M. Guisnet, N.S. Gnep, F. Alario, Appl. Catal. A Gen. 89, 1 (1992)

    Article  CAS  Google Scholar 

  16. C.R. Bayense, J.H.C. van Hooff, Appl. Catal. A Gen. 79, 127 (1991)

    Article  CAS  Google Scholar 

  17. V.R. Choudhary, K. Mantri, C. Sivadinarayana, Microporous Mesoporous Mater. 37, 1 (2000)

    Article  CAS  Google Scholar 

  18. V.R. Choudhary, A.K. Kinage, C. Sivadinarayana, M. Guisnet, J. Catal. 158, 23 (1996)

    Article  CAS  Google Scholar 

  19. J. Kanai, N. Kawata, Appl. Catal. 55, 115 (1989)

    Article  CAS  Google Scholar 

  20. M. Miyamoto, T. Kamei, N. Nishiyama, Y. Egashira, K. Ueyama, Adv. Mater. 17, 1985 (2005)

    Article  CAS  Google Scholar 

  21. D.V. Vu, M. Miyamoto, N. Nishiyama, S. Ichikawa, Y. Egashira, K. Ueyama, Microporous Mesoporous Mater. 115, 106 (2008)

    Article  CAS  Google Scholar 

  22. K. Mabuchi, M. Miyamoto, Y. Oumi, S. Uemiya, J. Jpn. Petrol. Inst. 54, 275 (2011)

    Article  CAS  Google Scholar 

  23. Y. Hirota, K. Murata, M. Miyamoto, Y. Egashira, N. Nishiyama, Catal. Lett. 140, 22 (2010)

    Article  CAS  Google Scholar 

  24. V.R. Choudhary, A.K. Kinage, C. Sivadinarayana, P. Devadas, S.D. Sansare, M. Guisnet, J. Catal. 158, 34 (1996)

    Article  CAS  Google Scholar 

  25. J.C. Groen, J.A. Moulijn, J. Pérez-Ramírez, J. Mater. Chem. 16, 2121 (2006)

    Article  CAS  Google Scholar 

  26. X. Wei, P.G. Smirniotis, Microporous Mesoporous Mater. 97, 97 (2006)

    Article  CAS  Google Scholar 

  27. J.C. Groen, W. Zhu, S. Brouwer, S.J. Huynink, F. Kapteijn, J.A. Moulijn, J. Pérez-Ramírez, J. Am. Chem. Soc. 129, 355 (2007)

    Article  CAS  Google Scholar 

  28. A. Čižmek, B. Subotić, I. Šmit, A. Tonejc, R. Aiello, F. Crea, A. Nastro, Microporous Mater. 8, 159 (1997)

    Article  Google Scholar 

  29. K. Nishi, S. Komai, K. Inagaki, A. Satsuma, T. Hattori, Appl. Catal. A 223, 187 (2002)

    Article  CAS  Google Scholar 

  30. N. Katada, T. Takeguchi, T. Suzuki, T. Fukushima, K. Inagaki, S. Tokunaga, H. Shimada, K. Sato, Y. Oumi, T. Sano, K. Segawa, K. Nakai, H. Shoji, P. Wu, T. Tatsumi, T. Komatsu, T. Masuda, K. Domen, E. Yoda, J.N. Kondo, T. Okuhara, Y. Kageyama, M. Niwa, M. Ogura, M. Matsukata, E. Kikuchi, N. Okazaki, M. Takahashi, A. Tada, S. Tawada, Y. Kubota, Y. Sugi, Y. Higashio, M. Kamada, Y. Kioka, K. Yamamoto, T. Shouji, Y. Arima, Y. Okamoto, H. Matsumoto, Appl. Catal. A 283, 63 (2005)

    Article  CAS  Google Scholar 

  31. B. Sulikowski, Z. Olejniczak, V.C. Corberan, J. Phys. Chem. 100, 10323 (1996)

    Article  CAS  Google Scholar 

  32. C. Bigey, B.-L. Su, J. Mol. Catal. A 209, 179 (2004)

    Article  CAS  Google Scholar 

  33. K.-J. Chao, P.-H. Liu, Catal. Surv. Asia 9, 11 (2005)

    Article  CAS  Google Scholar 

  34. B. Zheng, W. Hua, Y. Yue, Z. Gao, J. Catal. 232, 143 (2005)

    Article  CAS  Google Scholar 

  35. P.P. Man, J. Klinowski, Chem. Phys. Lett. 147, 581 (1988)

    Article  CAS  Google Scholar 

  36. N.S. Gnep, J.Y. Doyemet, A.M. Seco, F.R. Ribeiro, M. Guisnet, Appl. Catal. 35, 93 (1987)

    Article  CAS  Google Scholar 

  37. H. Kitagawa, Y. Sonoda, Y. Ono, J. Catal. 101, 12 (1987)

    Article  Google Scholar 

  38. H. Krannila, W.O. Haag, B.C. Gates, J. Catal. 135, 115 (1992)

    Article  CAS  Google Scholar 

  39. D.B. Lukyanov, N.S. Gnep, M.R. Guisnet, Ind. Eng. Chem. Res. 34, 516 (1995)

    Article  CAS  Google Scholar 

  40. R.J. Quann, L.A. Green, S.A. Tabak, F.J. Krambeck, Ind. Eng. Chem. Res. 27, 565 (1988)

    Article  CAS  Google Scholar 

  41. J.C. Vedrine, P. Dejaifve, E.D. Garbowski, E.G. Derouane, Stud. Surf. Sci. Catal. 5, 29 (1980)

    Article  CAS  Google Scholar 

  42. L.H. Nguyen, T. Vazhnova, S.T. Kolaczkowski, D.B. Lukyanov, Chem. Eng. Sci. 61, 5881 (2006)

    Article  CAS  Google Scholar 

  43. J.A. Biscardi, E. Iglesia, J. Physic. Chem. B 102, 9284 (1998)

    Article  CAS  Google Scholar 

  44. W.E. Garwood, A.C.S. Symp, Ser. 218, 383 (1983)

    CAS  Google Scholar 

  45. B.M. Weckhuysen, D. Wang, M.P. Rosynek, J.H. Lunsford, J. Catal. 175, 338 (1998)

    Article  CAS  Google Scholar 

  46. Y.H. Kim, R.W. Borry III, E. Iglesia, Microporous Mesoporous Mater. 35–36, 495 (2000)

    Article  Google Scholar 

  47. A.L. Lapidus, A.A. Dergachev, V.A. Kostina, A.A. Silakova, Petrol. Chem. 48, 83 (2008)

    Article  CAS  Google Scholar 

  48. Z. Popova, K. Aristirova, C. Dimitrov, React. Kinet. Catal. Lett. 41, 369 (1990)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is financially supported by A-STEP feasibility study program from Japan Science and Technology Agency (JST), and Grant for Research from The Japan Petroleum Institute.

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Authors and Affiliations

  1. Department of Chemistry and Biomolecular Science, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Manabu Miyamoto & Shigeyuki Uemiya

  2. Department of Materials Science and Technology, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Kota Mabuchi & Jun Kamada

  3. Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan

    Yuichiro Hirota & Norikazu Nishiyama

  4. Division of Instrument Analysis, Life Science Research Center, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Yasunori Oumi

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  1. Manabu Miyamoto
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  2. Kota Mabuchi
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Correspondence to Manabu Miyamoto.

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Miyamoto, M., Mabuchi, K., Kamada, J. et al. para-Selectivity of silicalite-1 coated MFI type galloaluminosilicate in aromatization of light alkanes. J Porous Mater 22, 769–778 (2015). https://doi.org/10.1007/s10934-015-9950-8

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