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Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane

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Abstract

Fe, Co, and Mn substituted AlPO-5 molecular sieves, including FeAPO-5, CoAPO-5, MnAPO-5, FeCoAPO-5, FeMnAPO-5, and CoMnAPO-5 were synthesized by hydrothermal method and characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), nitrogen adsorption, and Fourier transform infrared (FT-IR) spectroscopy. The lattice expansions were observed with Fe, Co, and/or Mn substitution of Al atom in AlPO-5. The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol (K/A oil) with molecular oxygen was studied over these catalysts at the reaction temperature of 403 K. The higher activities of the multi-metal substituted AlPO-5, compared to that of single metal substituted AlPO-5, were observed. The underlying reason for the superior activity of the multi-metal substituted AlPO-5 was analyzed.

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Acknowledgments

We are grateful to the National Natural Science Foundation of China (Grant: 20233040) and the National High Technology Research and Development Program of China for the financial support (Grant: 2004AA32G020).

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Correspondence to Jie Xu.

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Zhou, L., Xu, J., Chen, C. et al. Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane. J Porous Mater 15, 7–12 (2008). https://doi.org/10.1007/s10934-006-9045-7

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  • DOI: https://doi.org/10.1007/s10934-006-9045-7

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