Journal of Inorganic and Organometallic Polymers and Materials

, Volume 23, Issue 3, pp 766–770

Polycatenated Bilayer Structure Containing Honeycomb-like 63 Layers

Authors

  • Duan-Chuan Hou
    • State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum (Beijing)
    • Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences
  • Gui-Yuan Jiang
    • State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum (Beijing)
    • Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences
Communication

DOI: 10.1007/s10904-012-9815-4

Cite this article as:
Hou, D., Jiang, G. & Wang, F. J Inorg Organomet Polym (2013) 23: 766. doi:10.1007/s10904-012-9815-4

Abstract

A new luminescent Zn(II) compound, [Zn2(IN)3(bpy)0.5(CH3COO)]·2(DMA) (1, IN = isonicotinate, bpy = 4,4′-bipyridine, DMA = N,N-dimethylacetamide), was synthesized under solvothermal condition and structurally characterized by single crystal X-ray diffraction. Compound 1 features a (3,4)-connected bilayer structure with honeycomb-like 63 layers and bpy pillars. Each individual bilayer is catenated with two adjacent bilayers, giving rise to a rare 2D + 2D → 3D polycatenation motif.

Keywords

Solvothermal synthesis Metal-organic framework Polycantenation Luminescence

Supplementary material

10904_2012_9815_MOESM1_ESM.doc (221 kb)
Supplementary material 1 (DOC 221 kb)

Copyright information

© Springer Science+Business Media New York 2013