Hydrothermal Synthesis and Characterization of Trimethyltin(IV) Derivatives with 2-Carboxyethylphosphonic and Benzylphosphonic acid: X-ray Crystal Structures of 2D Network Polymers

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Abstract

Two organotin(IV) derivatives, {[(CH3)3Sn]6·[O3P(CH2)2CO2]2·3H2O} n 1 and {[(CH3)2Sn]4·[O3PCH2Ph]4} n 2, were synthesized by the reaction of trimethyltin(IV) chloride, 2-carboxyethylphosphonic acid and benzylphosphonic acid, respectively. Characterization of complexes 1 and 2 were achieved using elemental analysis, IR, TGA, NMR (1H, 13C, 31P and 119Sn) spectroscopy and X-ray crystallography diffraction analysis. X-ray characterization show that complexes 1 and 2 are 2D network structures.