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Direct Synthesis and Crystal Structure of Dehydrated State in Vapochromic MMX-type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes

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Abstract

The dehydrated vapochromic 1D coordination polymer, (H3NC4H8NH3)2[Pt2(pop)4I] (1) was synthesized directly from methanol solution. Although vapochromic 1 · 4H 2 O has been synthesized, dehydrated high-temperature structure has never been determined because of lowering the quality of crystal by dehydration. The crystal structure of 1 was determined by X-ray crystal structure analysis, and we confirmed that it was identical to the dehydrated high-temperature structure of 1 · 4H 2 O by comparing the powder X-ray diffraction (XRD) patterns. The Pt–I–Pt distance (d(Pt–I–Pt)) of compound 1 · 4H 2 O was shortened for approximately 1.1 Å by desorption of water to form compound 1, accompanied with phase transition in electronic states. The other crystal including methanol molecule as lattice solvent, 1 · 2MeOH, was also obtained as by-product. The synthesis from various kinds of organic solvent has the great potential to develop the field of vapochromism accompanying phase transition of electronic state.

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Acknowledgments

This work was partly supported by a Grant-in-Aid for Creative Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai, 980-8578, Japan

    Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka & Masahiro Yamashita

  2. Department of Advanced Material Science, Graduate School of Frontier Sciences, The University of Tokyo and CREST (JST), 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan

    Hiroyuki Matsuzaki & Hiroshi Okamoto

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  1. Hiroaki Iguchi
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  2. Shinya Takaishi
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  3. Takashi Kajiwara
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  4. Hitoshi Miyasaka
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  5. Masahiro Yamashita
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  6. Hiroyuki Matsuzaki
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  7. Hiroshi Okamoto
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Correspondence to Masahiro Yamashita.

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Iguchi, H., Takaishi, S., Kajiwara, T. et al. Direct Synthesis and Crystal Structure of Dehydrated State in Vapochromic MMX-type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes. J Inorg Organomet Polym 19, 85–90 (2009). https://doi.org/10.1007/s10904-008-9242-8

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  • DOI: https://doi.org/10.1007/s10904-008-9242-8

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