Abstract
Two novel chiral organic–inorganic hybrid materials based on two important heteropolyoxometallate namely Preyssler and Wells–Dawson anions, (Hval)2(Hgly)(H3O)6K5[Na(H2O)P5W30O110]·19.5H2O (1) and (Hpro)6[P2W18O62]·8H2O (2), were prepared and characterized by elemental analysis, X-ray diffraction, and infrared spectroscopy. The mixed amino acid as cations, Preyssler and Wells–Dawson as anions held together into a 3D-network through hydrogen-bonding interactions. The most unique structural features of 1 and 2 are their 3D-inorganic infinite tunnel-like framework. It results a weak van der Waals interlayer interaction. This provides a desirable condition to use its potential as a host in a host–guest complex. The chirallity for these two crystal structures, with the space group P21 has been observed. The electrostatic forces and hydrogen bonding, keep these ‘‘adducts’’ stable in the solid state.
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U. Kortz, A. Müller, J. van Slageren, J. Schnack, N. S. Dalal, and M. Dressel (2009). Coord. Chem. Rev. 253, 2315.
M. T. Pope Heteropoly and isopoly oxometalates (Springer-Verlag, Heidelberg, 1983).
C. R. Kagan, D. B. Mitzi, and C. D. Dimitrakopoulos (1999). Science 286, 945.
M. H. Alizadeh, S. P. Harmalker, Y. Jeannin, J. Martin-Frere, and M. T. Pope (1985). J. Am. Chem. Soc. 107, 2662.
M. H. Alizadeh, K. T. Holman, M. Mirzaei, and H. Razavi (2006). Polyhedron 25, 1567.
M. H. Alizadeh, H. Eshtiagh-Hosseini, and R. Khoshnavazi (2004). J. Mol. Struct. 688, 33.
H. An, Y. Lan, Y. Li, E. B. Wang, N. Hao, D. Xiao, L. Duan, and L. Xu (2004). Inorg. Chem. Commun. 7, 356.
M. H. Alizadeh, M. Mirzaei, and H. Razavi (2008). Mater. Res. Bull. 43, 546.
M. H. Alizadeh, R. Tayebee, and M. Mirzaei (2008). Cryst. Res. Technol. 43, 214.
M. H. Alizadeh, H. Eshtiagh-Hosseini, M. Mirzaei, A. R. Salimi, and H. Razavi (2008). Struct. Chem. 19, 155.
M. H. Alizadeh, M. Mirzaei, A. R. Salimi, and H. Razavi (2009). Mater. Res. Bull. 44, 1515.
F. Yao, Y.-G. Chen, A. R. Salimi, and M. Mirzaei (2011). J. Clust. Sci. 22, 309.
M. H. Alizadeh, H. Eshtiagh-Hosseini, M. Mirzaei, and M. Hosseini-Nejad (2009). Polish. J. Chem. 83, 1583.
X. D. Yang, Y.-G. Chen, M. Mirzaei, A. R. Salimi, and F. Yao (2009). Inorg. Chem. Commun. 12, 195.
P. Y. Chou and G. D. Fasman (1974). Biochemistry 13, 222.
L. Ouahab, M. Bencharif, and D. Grandjean, CR Acad. Sci. Paris 307, série II, 749 (1988) 26
L. Ouahab (1998). Coord. Chem. Rev. 178–180, 1501.
S. Triki, L. Ouahab, J. Padiou, and D. Grandjean (1989) J. Chem. Soc. Chem. Commun. 1068
J. M. Clemente-Juan and E. Coronado (1999). Coord. Chem. Rev. 193–195, 361.
P. Le Maguerés, L. Ouahab, S. Golhen, D. Grandjean, O. Pena, J. Jegaden, C. J. Gomez-Garcia, and P. Delhaes (1994). Inorg. Chem. 33, 5180.
D. Attanasio and F. Bachechi (1994). Adv. Mater. 6(2), 145.
J. Niu, X. You, C. Duan, H. Fun, and Z. Zhou (1996). Inorg. Chem. 35, 4211.
L. Zhang, Y. Zhou, Z. Yu, G. Fang, and X. You (2001). J. Mol. Struct. 570, 83.
Z. Han, E. Wang, G. Luan, Y. Li, H. Zhang, Y. Duan, C. Hu, and N. Hu (2002). J. Mater. Chem. 12, 1169.
T. Yamase (1998). Chem. Rev. 98, 307.
M. Nikpour, H. Eshtiagh-Hosseini, M. Mirzaei, A. Aghaei Kaju, Y.-G. Chen, and S. Zarinabadi (2010). Chin. Chem. Lett. 21, 501.
M. Nikpour, M. Mirzaei, Y.-G. Chen, A. Aghaei Kaju, and M. Bakavoli (2009). Inorg. Chem. Commun. 12, 879.
H. Y. An, E. B. Wang, D. R. Xiao, Y. G. Li, Z. M. Su, and L. Xu (2006). Angew. Chem. Int. Ed. 45, 904.
G. Baronetti, L. Briand, U. Sedran, and H. Thomas (1998). Appl. Catal. A Gen. 172, 265.
Bruker. SAINTPlus, v. 6.2. Data Reduction and Correction Program (Bruker AXS, Madison, 2001)
Bruker. APEX2 software package, v. 1.27. Bruker Molecular Analysis Research Tool (Bruker AXS, Madison, 2005)
G. M. Sheldrick SADABS, v. 2.03, Bruker/siemens area detector absorption correction program (Bruker AXS, Madison, 2003).
G. M. Sheldrick SHELXTL, v. 6.12, structure determination software suite (Bruker AXS, Madison, 2001).
H. Aghabozorg, H. Eshtiagh-Hosseini, A. R. Salimi, and M. Mirzaei (2010). J. Iran. Chem. Soc. 7, 289.
J. T. Rhule, C. L. Hill, D. A. Judd, and R. F. Schinazi (1998). Chem. Rev. 98, 327.
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The authors wish to thank to the Ferdowsi University of Mashhad for financial support of this article (Grant No. 17897/2).
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Eshtiagh-Hosseini, H., Mirzaei, M. Two Novel Chiral Inorganic–Organic Hybrid Materials Containing Preyssler and Wells–Dawson Heteropolyoxometallates with Valine (val), Glycine (gly), and Proline (pro) Amino acids: (Hval)2(Hgly)(H3O)6K5[Na(H2O)P5W30O110]·19.5H2O and (Hpro)6[P2W18O62]·8H2O. J Clust Sci 23, 345–355 (2012). https://doi.org/10.1007/s10876-011-0434-y
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DOI: https://doi.org/10.1007/s10876-011-0434-y