Abstract
This work presents the problem of changes in distances between oxygen atoms (ions), depending on the metal type, metal charge, polarization capabilities, composition and crystallographic structure using metal oxides as an example. Changes in ion packing density in oxides have been also presented. It has been shown that these changes depend not only on ionic radii, but also on the interaction character (interatomic bonds).
Graphical Abstract
It has been shown that changes in ion packing density and distances between oxygen atoms (ions) depend not only on ionic radii, but also on the character of their interactions (interatomic bonds). Fig. The dependence of the packing density of a series of metal oxides with compact structures on the ionic radii.
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Stokłosa, A., Laskowska, B. Influence of Ionic Interactions and Ion Sizes on Their Packing Density in Metal Oxides. J Chem Crystallogr 41, 1935–1939 (2011). https://doi.org/10.1007/s10870-011-9984-y
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DOI: https://doi.org/10.1007/s10870-011-9984-y