Journal of Materials Science

, Volume 40, Issue 14, pp 3709–3714

Effect of processing parameters on the particle size and stabilisation of titania sols

  • M. C. Cordero-Cabrera
  • G. S. Walker
  • D. M. Grant
Article

DOI: 10.1007/s10853-005-2825-7

Cite this article as:
Cordero-Cabrera, M.C., Walker, G.S. & Grant, D.M. J Mater Sci (2005) 40: 3709. doi:10.1007/s10853-005-2825-7

Abstract

A systematic analysis of the main parameters affecting the characteristics of titania sols for photocatalytic applications prepared from the hydrolysis of titanium i-propoxide (TIP) is presented. Stable monomodal sols were obtained at peptization temperatures between 50C and 70C, for water/alkoxide molar ratios ranging from 250 to 1000 and acid/alkoxide molar ratios ranging from 0.4 to 0.7. Unstable sols with bimodal distributions were obtained at higher peptization temperatures. The peptization temperature was the parameter with the greatest influence, followed by acid concentration, whereas the water/alkoxide ratio showed little influence. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) were used to verify the primary particle size as measured by photon correlation spectroscopy (PCS). The observations are explained using the Derjaguin, Landau, Verwey and Overbeek (DLVO) theory on suspension stability.

Copyright information

© Springer Science + Business Media, Inc. 2005

Authors and Affiliations

  • M. C. Cordero-Cabrera
    • 1
  • G. S. Walker
    • 1
    • 2
  • D. M. Grant
    • 1
  1. 1.Advanced Materials Research Group, School of Mechanical, Materials, Manufacturing and EngineeringUniversity of NottinghamUK
  2. 2.Department of Materials Science and MetallurgyUniversity of CambridgeCambridgeUK