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Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K

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Abstract

The densities, ρ, and speeds of sound, u, have been measured as a function of composition for binary liquid mixtures of dipropylene glycol monopropyl ether (DPGMPE) with n-butylamine (BA), dibutylamine (DBA), and tributylamine (TBA) at (288.15, 293.15, 298.15, 303.15, and 308.15) K and atmospheric pressure using an Anton Paar DSA-5000 instrument. The ρ and u values were used to calculate excess molar volumes, V E, deviations from the ideal behavior of the thermal expansion coefficient, α E, and the isentropic compressibilities, Δκ S . Moreover, the apparent molar volume \({\bar{{V}}_{\phi ,i}^0 }\), and apparent molar compressibility \({\bar{{K}}_{\phi ,i}^0 }\), of the components have been calculated at infinite dilution. The Jouyban–Acree model is used to correlate the experimental values of density and ultrasonic speed at different temperatures.

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, 136119, India

    Amalendu Pal & Rekha Gaba

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  1. Amalendu Pal
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  2. Rekha Gaba
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Pal, A., Gaba, R. Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K. Int J Thermophys 30, 862–882 (2009). https://doi.org/10.1007/s10765-009-0593-3

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