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Mössbauer and XRD study of intercalated CaFe-layered double hydroxides

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Abstract

N-containing fully saturated (L-prolinate) or aromatic (indole-2-carboxylate) heterocyclic anions were immobilised in CaFe-layered double hydroxide with the dehydration-rehydration method from aqueous ethanol or acetone. The structure of the resulting organic-inorganic hybrids was characterised mainly with powder X-ray diffraction and 57Fe Mössbauer spectroscopy, and as supplementary analysis scanning electron microscopy, energy dispersive X-ray spectroscopy with elemental mapping and molecular modelling were also applied. It was found that the solvent mixture used for the synthesis caused enormous difference in the interlayer spacings of the obtained inorganic-organic hybrids.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, University of Szeged, Szeged, Hungary

    Mónika Sipiczki & Pál Sipos

  2. Material and Solution Structure Research Group, Institute of Chemistry, University of Szeged, Szeged, Hungary

    Mónika Sipiczki, István Pálinkó & Pál Sipos

  3. Institute of Chemistry, Eötvös Loránd University, Budapest, Hungary

    Ernő Kuzmann & Zoltán Homonnay

  4. Department of Organic Chemistry, University of Szeged, Szeged, Hungary

    István Pálinkó

  5. MTA-SZTE “Lendület” Porous Nanocomposites Research Group, University of Szeged, Szeged, Hungary

    Ákos Kukovecz

  6. Department of Applied and Environmental Chemistry, University of Szeged, Szeged, Hungary

    Ákos Kukovecz & Zoltán Kónya

  7. MTA-SZTE Reaction Kinetics and Surface Chemistry Research Group, University of Szeged, Szeged, Hungary

    Zoltán Kónya

Authors
  1. Mónika Sipiczki
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  2. Ernő Kuzmann
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  3. István Pálinkó
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  4. Zoltán Homonnay
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  5. Pál Sipos
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  6. Ákos Kukovecz
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  7. Zoltán Kónya
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Corresponding author

Correspondence to Ernő Kuzmann.

Additional information

Proceedings of the 32nd International Conference on the Applications of the Mössbauer Effect (ICAME 2013) held in Opatija, Croatia, 1–6 September 2013.

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Sipiczki, M., Kuzmann, E., Pálinkó, I. et al. Mössbauer and XRD study of intercalated CaFe-layered double hydroxides. Hyperfine Interact 226, 171–179 (2014). https://doi.org/10.1007/s10751-013-0925-3

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  • DOI: https://doi.org/10.1007/s10751-013-0925-3

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