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Polymer-Supported N-Hydroxyphthalimide as Catalyst for Toluene and p-Methoxytoluene Aerobic Oxidation

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Abstract

In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solvent-free system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.

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Acknowledgments

Financial assistance from the National Science Centre of Poland (Grant No. N N209 755 440) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Krzywoustego 4, 44 100, Gliwice, Poland

    Kornela Kasperczyk, Beata Orlinska & Jan Zawadiak

  2. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Kraków, Poland

    Ewa Witek, Piotr Łątka & Leonard Proniewicz

Authors
  1. Kornela Kasperczyk
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  2. Beata Orlinska
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  3. Ewa Witek
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  4. Piotr Łątka
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  5. Jan Zawadiak
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  6. Leonard Proniewicz
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Corresponding author

Correspondence to Beata Orlinska.

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Kasperczyk, K., Orlinska, B., Witek, E. et al. Polymer-Supported N-Hydroxyphthalimide as Catalyst for Toluene and p-Methoxytoluene Aerobic Oxidation. Catal Lett 145, 1856–1867 (2015). https://doi.org/10.1007/s10562-015-1578-4

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  • DOI: https://doi.org/10.1007/s10562-015-1578-4

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