Catalysis Letters

, Volume 144, Issue 7, pp 1313–1321

Amino-Functional Imidazolium Ionic Liquids for CO2 Activation and Conversion to Form Cyclic Carbonate

Article

DOI: 10.1007/s10562-014-1241-5

Cite this article as:
Yue, C., Su, D., Zhang, X. et al. Catal Lett (2014) 144: 1313. doi:10.1007/s10562-014-1241-5

Abstract

A series of amino-functional imidazolium ionic liquids have been prepared and used as catalysts for cycloaddition of CO2 with epoxide. The reactions generated the cyclic carbonate even at room temperature under atmospheric pressure. Under the optimal reaction conditions, the propylene carbonate was yield to 98.0 % in the presence of [APbim]I, and the ionic liquids could be reused at least nine times without noticeable decrease in activity and selectivity. Besides, the reaction mechanism was proposed.

Graphical Abstract

Cycloaddition of CO2 with epoxides catalyzed by amino-functionalized imidazolium ionic liquid can achieve CO2 activation and conversion directly. The reactions generated the corresponding products even at room temperature under atmospheric pressure. Amino-functionalized imidazolium ionic liquid has showed excellent catalytic activity, reusability and general applicability.
https://static-content.springer.com/image/art%3A10.1007%2Fs10562-014-1241-5/MediaObjects/10562_2014_1241_Figa_HTML.gif

Keywords

Amino-functional imidazolium ionic liquidsCarbon dioxideEpoxideCyclic carbonate

Supplementary material

10562_2014_1241_MOESM1_ESM.docx (778 kb)
Supplementary material 1 (DOCX 778 kb)

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang ProvinceHeilongjiang UniversityHarbinPeople’s Republic of China
  2. 2.International Joint Research Center of Catalysis TechnologyHeilongjiang UniversityHarbinPeople’s Republic of China
  3. 3.School of Chemistry and Material ScienceHeilongjiang UniversityHarbinPeople’s Republic of China