Aquatic Geochemistry

, Volume 14, Issue 3, pp 263–288

Increasing Iron Concentrations in UK Upland Waters

Authors

    • Centre for Ecology and Hydrology Wallingford
  • S. Lofts
    • Centre for Ecology and Hydrology LancasterLancaster Environment Centre
  • C. D. Evans
    • Centre for Ecology and Hydrology Bangor
  • B. Reynolds
    • Centre for Ecology and Hydrology Bangor
  • E. Tipping
    • Centre for Ecology and Hydrology LancasterLancaster Environment Centre
  • M. Neal
    • Centre for Ecology and Hydrology Wallingford
Original Paper

DOI: 10.1007/s10498-008-9036-1

Cite this article as:
Neal, C., Lofts, S., Evans, C.D. et al. Aquat Geochem (2008) 14: 263. doi:10.1007/s10498-008-9036-1

Abstract

Iron distributions in rainfall, streams, soils and groundwaters are described for the Upper River Severn catchment of mid-Wales. Iron is mainly supplied from within-catchment sources with highest concentrations occurring under reducing conditions. Iron concentrations have doubled over the past 20 years (~5.0 μg yr−1 for the forest and ~3.7 μg yr−1 for the moorland). For the forested sites, the gradients are particularly high post-1993. UK rivers/lakes monitored by the UK Acid Waters Monitoring Network show similar increases. Generally, Fe correlates with dissolved organic carbon (DOC). The greatest rates of Fe increase coincide with those for DOC. Thermodynamic modelling using WHAM/Model VI indicates that Fe(III) is mainly in microparticulate form (probably oxyhydroxides) apart from under reducing conditions. It is proposed that Fe increases for surface waters are associated with increased microparticulate Fe(III) due to stabilisation against aggregation by binding of DOM to its surface. The results relate to acidification declines and deforestation leading to land disturbance and wetter conditions within the soil. There will be greater acidification reversal following tree harvesting due to lowering of atmospheric SOx scavenging and this may have resulted in the greater increase in Fe in the later years of the study.

Keywords

IronRiverAcidificationColloids/nanoparticlesDOCWHAM

Copyright information

© Springer Science+Business Media B.V. 2008