Summary.
The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.
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Corresponding author. E-mail: koning@iacgu7.chemie.uni-mainz.de
Received April 8, 2002; accepted April 18, 2002
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van Koningsbruggen, P., Grunert , M. & Weinberger, P. Spin Transition of 1D, 2D and 3D Iron(II) Complex Polymers The Tug-of-War between Elastic Interaction and a Shock-Absorber Effect . Monatshefte für Chemie 134, 183–198 (2003). https://doi.org/10.1007/s00706-002-0492-9
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DOI: https://doi.org/10.1007/s00706-002-0492-9