Microchimica Acta

, Volume 169, Issue 1, pp 73–78

Chemiluminescence reactions of luminol system catalyzed by nanoparticles of a gold/silver alloy

Authors

    • College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Key Laboratory of Molecule-based MaterialsAnhui Normal University
  • Shanjun Tao
    • College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Key Laboratory of Molecule-based MaterialsAnhui Normal University
  • Fenfen Wang
    • College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Key Laboratory of Molecule-based MaterialsAnhui Normal University
  • Jianguo Hong
    • College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Key Laboratory of Molecule-based MaterialsAnhui Normal University
  • Xianwen Wei*
    • College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Key Laboratory of Molecule-based MaterialsAnhui Normal University
Original Paper

DOI: 10.1007/s00604-010-0302-8

Cite this article as:
Li, S., Tao, S., Wang, F. et al. Microchim Acta (2010) 169: 73. doi:10.1007/s00604-010-0302-8

Abstract

The chemiluminescence (CL) of luminol–H2O2 system is strongly enhanced on addition of nanoparticles composed of a gold/silver alloy (ratio 5:4). The effect is attributed to a catalytically enhanced decomposition of H2O2 to produce reactive oxygen species. A reaction mechanism is proposed. Organic compounds containing hydroxy, amino, or thiol groups (such as amino acids, dopamine, pyrocatechol) can inhibit the CL signal of the system. It is concluded that the system has a large potential in terms of the determination of such compounds.

Keywords

Flow injection Chemiluminescence Luminol Au–Ag alloy nanoparticles

Supplementary material

604_2010_302_MOESM1_ESM.doc (656 kb)
ESM 1 (DOC 655 kb)

Copyright information

© Springer-Verlag 2010