, Volume 40, Issue 4, pp 317-321

Thermodynamic admissibility of the pompon model for branched polymers

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Abstract

The pompon model for branched polymers is re-formulated within a general framework of nonequilibrium thermodynamics. While the original model of McLeish and Larson is found to be thermodynamically admissible, nonequilibrium thermodynamics strongly suggests several model modifications. As an immediate consequence, a nonzero second normal-stress coefficient in shear flow is predicted by the modified pompon model.

Received: 12 April 2000 Accepted: 11 September 2000