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Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS

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Abstract

The deformation behavior is closely related to the structures and mechanical properties of polymers. The structural evolution during deformation is fundamental to understand the deformation mechanism and control the properties of polymers. Deformation-induced structure transitions contain a stable structure to metastable one or metastable structure to a stable one. The structures of the uniaxially stretched poly(butylene succinate) (PBS) at different temperatures were directly investigated by in situ synchrotron wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). The data reveal the initial strain of the α-β transition increases with the stretching temperatures. A quantitative analysis was performed to explore the crystal transition mechanisms of the stretched PBS.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (51173130, 21274149, and 21374077).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, People’s Republic of China

    Wenyang Zhang, Chengbo Zhou, Yao Zhang, Feifei Xue, Baojing Luo, Jingqing Li, Yingrui Shang & Shichun Jiang

  2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, People’s Republic of China

    Hongfei Li

  3. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, People’s Republic of China

    Xiangkui Ren

  4. Institute of High Energy Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Zhonghua Wu

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  1. Wenyang Zhang
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  11. Shichun Jiang
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Correspondence to Shichun Jiang.

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Zhang, W., Zhou, C., Zhang, Y. et al. Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS. Colloid Polym Sci 294, 321–328 (2016). https://doi.org/10.1007/s00396-015-3789-z

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  • DOI: https://doi.org/10.1007/s00396-015-3789-z

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