Colloid and Polymer Science

, 285:1733

Organic–inorganic nanocomposites prepared from fluoro-aramid and silica

  • Muhammad Ilyas Sarwar
  • Sonia Zulfiqar
  • Zahoor Ahmad
Short Communication

DOI: 10.1007/s00396-007-1760-3

Cite this article as:
Sarwar, M.I., Zulfiqar, S. & Ahmad, Z. Colloid Polym Sci (2007) 285: 1733. doi:10.1007/s00396-007-1760-3

Abstract

Fluoro-aramid-based sol/gel-derived nanocomposites were synthesized by condensing a mixture of 4,4′-(hexafluoro-isopropylidene)dianiline and 1,3-phenylenediamine with terephthaloylchloride (TPC) in dimethylacetamide. TPC was added in slight excess to produce amide chains with carbonyl chloride end groups and then replaced with alkoxy groups using aminophenyltrimethoxysilane to develop bonding with the silica network. Mechanical, dynamic mechanical thermal, water absorption and morphological measurements were carried out on the thin hybrid films. Increase in the tensile strength and modulus was observed as compared to pristine polyamide. The thermal decomposition temperature was found in the range of 400–500 °C. The water absorption was found to be reduced with higher silica content. The glass transition temperature and the storage moduli increased with increasing silica concentration. The maximum increase in the Tg value (345 °C) was observed with 20 wt% silica. Scanning electron microscopy revealed the uniform distribution of silica in the matrix with an average particle size ranging from 8 to 50 nm.

Keywords

AramidNanocompositesSol–gel processStress-strain curvesGlass transition temperatureMorphology

Copyright information

© Springer-Verlag 2007

Authors and Affiliations

  • Muhammad Ilyas Sarwar
    • 1
  • Sonia Zulfiqar
    • 1
  • Zahoor Ahmad
    • 2
  1. 1.Department of ChemistryQuaid-i-Azam UniversityIslamabadPakistan
  2. 2.Department of Chemistry, Faculty of ScienceKuwait UniversitySafatKuwait