Applied Physics B

, Volume 74, Issue 6, pp 569–575

Wavelength-modulation spectroscopy using a frequency-doubled current-modulated diode laser

  • G. Hancock
  • V.L. Kasyutich
  • G.A.D. Ritchie

DOI: 10.1007/s003400200863

Cite this article as:
Hancock, G., Kasyutich, V. & Ritchie, G. Appl Phys B (2002) 74: 569. doi:10.1007/s003400200863

Abstract.

We have studied atomic absorption in an argon discharge by wavelength-modulation spectroscopy with a frequency-doubled diode laser. The tunable wavelength-modulated radiation at 430 nm was generated by frequency doubling a current-modulated 860-nm diode laser in a KNbO3 crystal. 2f-, 4f- and 6f-harmonic spectra as a function of diode laser modulation depth were measured on a Doppler-broadened sample of excited argon atoms produced in a capacitively coupled plasma chamber. Characterisation of the harmonic signals was accomplished. Minimum detectable absorbances of 7.7×10-5 and 1.9×10-4 based on a 3σ criterion (σ being the standard deviation of the noise) were estimated for 2f- and 4f-harmonic detection of the frequency-doubled radiation with a time constant of 0.1 s. The concentrations of argon in the 1s4 state were found to be in the range of 3×108 to 1.2×1011 cm-3 for the experimental conditions studied.

PACS: 42.55.Px; 42.62.Fi; 42.65.Ky; 42.70.Mp

Copyright information

© Springer-Verlag 2002

Authors and Affiliations

  • G. Hancock
    • 1
  • V.L. Kasyutich
    • 1
  • G.A.D. Ritchie
    • 1
  1. 1.Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UKGB