Applied Physics B

, Volume 89, Issue 4, pp 459–467

Cavity cooling of translational and ro-vibrational motion of molecules: ab initio-based simulations for OH and NO

  • M. Kowalewski
  • G. Morigi
  • P.W.H. Pinkse
  • R. de Vivie-Riedle
Article

DOI: 10.1007/s00340-007-2860-y

Cite this article as:
Kowalewski, M., Morigi, G., Pinkse, P. et al. Appl. Phys. B (2007) 89: 459. doi:10.1007/s00340-007-2860-y

Abstract

We present detailed calculations on the basis of our recent proposal for simultaneous cooling of the rotational, vibrational and external molecular degrees of freedom [1]. In this method, the molecular ro-vibronic states are coupled by an intense laser and an optical cavity via coherent Raman processes enhanced by the strong coupling with the cavity modes. For a prototype system, OH, we showed that the translational motion is cooled to a few μK and the molecule is brought to the internal ground state in about a second. Here, we investigate numerically the dependence of the cooling scheme on the molecular polarizability, selecting NO as a second example. Furthermore, we demonstrate the general applicability of the proposed cooling scheme to initially vibrationally and rotationally hot molecular systems.

Copyright information

© Springer-Verlag 2007

Authors and Affiliations

  • M. Kowalewski
    • 1
  • G. Morigi
    • 2
  • P.W.H. Pinkse
    • 3
  • R. de Vivie-Riedle
    • 1
  1. 1.Department of ChemistryLudwig-Maximilian-Universität MünchenMünchenGermany
  2. 2.Departament de FisicaUniversitat Autonoma de BarcelonaBellaterra (Barcelona)Spain
  3. 3.Max-Planck-Institut für QuantenoptikGarchingGermany