Article

Applied Physics B

, Volume 87, Issue 4, pp 717-722

First online:

Spectroscopic properties of neodymium doped high silica glass and aluminum codoping effects on the enhancement of fluorescence emission

  • Y. QiaoAffiliated withPhoto Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of SciencesGraduate School of the Chinese Academy of Sciences
  • , N. DaAffiliated withPhoto Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences
  • , D. ChenAffiliated withPhoto Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences Email author 
  • , Q. ZhouAffiliated withPhoto Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences
  • , J. QiuAffiliated withPhoto Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of SciencesCollege of Materials Science and Chemical Engineering, Zhejiang University
  • , T. AkaiAffiliated withNational Institute of Advanced Industrial Science and Technology Osaka

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Abstract

Nd3+-codoped and Al3+-Nd3+-codoped high silica glasses have been prepared by sintering nanoporous glasses impregnated with Nd3+ and Al3+ ions. The Judd–Ofelt intensity parameters Ω2,4,6 of Nd3+-doped high silica glasses were obtained and used to analyze aluminum codoping effects. Fluorescence properties of Nd3+-doped high silica glasses strongly depend on the Al3+ concentration. While Nd3+ ion absorption and emission intensities of obviously increase when aluminum is added to Nd3+-doped high silica glasses, fluorescence lifetimes decrease and aluminum codoping has almost no influence on the radiative quantum efficiencies. This indicates that aluminum codoping is responsible for an anti-quenching effect through a local modification of rare-earth environments rather than through physical cluster dispersion.