Polymer Bulletin

, Volume 69, Issue 3, pp 273–289

Synthesis and characterization of new polyfluorene derivatives: using phenanthro[9,10-d]imidazole group as a building block for deep blue light-emitting polymer

  • Zhiming Wang
  • Zhao Gao
  • Shanfeng Xue
  • Yulong Liu
  • Wensi Zhang
  • Cheng Gu
  • Fangzhong Shen
  • Ping Lu
  • Yuguang Ma
Original Paper

DOI: 10.1007/s00289-012-0710-5

Cite this article as:
Wang, Z., Gao, Z., Xue, S. et al. Polym. Bull. (2012) 69: 273. doi:10.1007/s00289-012-0710-5
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Abstract

A series of novel polyfluorene derivatives P1/4, P2/4, and P3/4, containing phenanthro[9,10-d]imidazole group on backbone are designed, synthesized, and well characterized. They all show high-molecular weights, good solubilities, and excellent thermal stabilities. The CV results of all three compounds show the lower LUMO levels and higher HOMO levels than PF. Among them, P3/4 exhibits deep blue emission both in solution and in solid state. The PLED based on P3/4 shows higher device performance and locates in the deep blue region with a CIE coordinate of (0.17, 0.08).

Keywords

Deep blue emissionPhenanthrenequinoneImidazoleMultifunctionalPolymer

Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • Zhiming Wang
    • 1
    • 2
  • Zhao Gao
    • 1
  • Shanfeng Xue
    • 1
  • Yulong Liu
    • 1
  • Wensi Zhang
    • 1
  • Cheng Gu
    • 1
  • Fangzhong Shen
    • 1
  • Ping Lu
    • 1
  • Yuguang Ma
    • 1
  1. 1.State Key Laboratory of Supramolecular Structure and MaterialsJilin UniversityChangchunPeople’s Republic of China
  2. 2.School of Petrochemical EngineeringShenyang University of TechnologyLiaoyangPeople’s Republic of China