Polymer Bulletin

, Volume 68, Issue 8, pp 2107–2119

Synthesis and photovoltaic properties of alternative copolymers of benzo[1,2-b:4,5-b′]dithiophene and thiophene

Authors

  • Jie Min
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Bo Peng
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Youjun He
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Maojie Zhang
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Zhi-Guo Zhang
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Jing Zhang
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Xia Guo
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Chaohua Cui
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
  • Dan Deng
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
    • Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic SolidsInstitute of Chemistry, Chinese Academy of Sciences
Original Paper

DOI: 10.1007/s00289-011-0672-z

Cite this article as:
Min, J., Peng, B., He, Y. et al. Polym. Bull. (2012) 68: 2107. doi:10.1007/s00289-011-0672-z

Abstract

Two conjugated polymers containing benzodithiophene (BDT) unit and the unit of thiophene or thieno[3,2-b]thiophene, P(BDT-T) and P(BDT-TT), were synthesized by Pd-catalyzed Stille coupling method. The UV–Vis absorption, thermal, and electrochemical properties of the two polymers were characterized. Photovoltaic properties of the polymers were studied by using the polymers as donor and PC70BM as acceptor with a weight ratio of polymer: PC70BM of 1:1.5. The power conversion efficiencies of the PSC devices based on P(BDT-T) reached 2.05% with an open-circuit voltage of 0.75 V, a short-circuit current of 4.5 mA cm−2, and a fill factor of 0.61, under the illumination of AM1.5, 100 mW cm−2.

Keywords

Benzodithiophene Conjugated polymers Polymer solar cells

Copyright information

© Springer-Verlag 2011