Conference contribution

Fresenius' Journal of Analytical Chemistry

, Volume 364, Issue 5, pp 495-498

First online:

Strategies for isotope ratio measurements with a double focusing sector field ICP-MS

  • M. HamesterAffiliated withFinnigan MAT GmbH, Barkhausenstrasse 2, D-28197 Bremen, Germany
  • , D. WiederinAffiliated withFinnigan MAT GmbH, Barkhausenstrasse 2, D-28197 Bremen, Germany
  • , J. WillsAffiliated withFinnigan MAT GmbH, Barkhausenstrasse 2, D-28197 Bremen, Germany
  • , W. KerlAffiliated withFinnigan MAT GmbH, Barkhausenstrasse 2, D-28197 Bremen, Germany
  • , C. B. DouthittAffiliated withFinnigan MAT GmbH, Barkhausenstrasse 2, D-28197 Bremen, Germany

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Abstract

A single collector double focusing sector field ICP-MS is evaluated for the determination of isotope ratios. Spectral interferences (e.g. 40Ar23Na on 63Cu) can lead to calculation of inaccurate ratios. The use of high resolution enables such interferences to be separated from the isotopes of interest. External reproducibilities of < 0.02% are shown for uninterfered isotopes (measured at low resolution R = 300) and < 0.1% for interfered isotopes which required the use of medium (R = 4000) and high resolution (R = 10000).