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Study of the dynamics of surface molecules by time-resolved sum-frequency generation spectroscopy

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Abstract

Sum-frequency generation (SFG) is a nonlinear laser-spectroscopy technique suitable for analysis of adsorbed molecules. The sub-monolayer sensitivity of SFG spectroscopy enables vibrational spectra to be obtained with high specificity for a variety of molecules on a range of surfaces, including metals, oxides, and semiconductors. The use of ultra-short laser pulses on time-scales of picoseconds also makes time-resolved measurements possible; this can reveal ultrafast transient changes in molecular arrangements. This article reviews recent time-resolved SFG spectroscopy studies revealing site-hopping of adsorbed CO on metal surfaces and the dynamics of energy relaxation at water/metal interfaces.

Time-resolved sum frequency generation spectroscopy at surfaces with non-resonant laser pulse irradiation

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Authors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuda, Midori-ku, Yokohama, 226-8503, Japan

    Jun Kubota

  2. Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

    Kazunari Domen

Authors
  1. Jun Kubota
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  2. Kazunari Domen
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Correspondence to Jun Kubota.

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Kubota, J., Domen, K. Study of the dynamics of surface molecules by time-resolved sum-frequency generation spectroscopy. Anal Bioanal Chem 388, 17–27 (2007). https://doi.org/10.1007/s00216-006-0957-5

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