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Methods for reactive oxygen species (ROS) detection in aqueous environments

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Abstract

This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): 1O2, O ·−2 /HOO·, H2O2, HO·, and CO ·−3 in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.

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Acknowledgments

The authors would like to acknowledge valuable comments of the anonymous reviewers and the associate editor which significantly improved the manuscript. This work was supported in part by the US National Science Foundation, Grant no. OCE 0752473 and the College of Arts and Sciences at the University of South Carolina. This is publication 72 of the University of California Irvine, Urban Water Research Center.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29229, USA

    Justina M. Burns & John L. Ferry

  2. Department of Civil and Environmental Engineering, University of California, Irvine, Irvine, CA, 92697, USA

    William J. Cooper

  3. Department of Chemistry, Colby College, Waterville, ME, 04901, USA

    D. Whitney King & Brian P. DiMento

  4. Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092, Zurich, Switzerland

    Kristopher McNeill

  5. Civil and Environmental Engineering, University of New South Wales, Sydney, NSW, 2052, Australia

    Christopher J. Miller & T. David Waite

  6. Department of Marine Sciences, University of Georgia, Athens, GA, 30602, USA

    William L. Miller

  7. Chemistry Department, University of Otago, Dunedin, 9054, New Zealand

    Barrie M. Peake & Steven A. Rusak

  8. Southern Cross GeoScience, Southern Cross University, Lismore, 2480, Australia

    Andrew L. Rose

Authors
  1. Justina M. Burns
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  2. William J. Cooper
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  3. John L. Ferry
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  4. D. Whitney King
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  5. Brian P. DiMento
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  6. Kristopher McNeill
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  7. Christopher J. Miller
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  8. William L. Miller
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  9. Barrie M. Peake
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  10. Steven A. Rusak
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  11. Andrew L. Rose
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  12. T. David Waite
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Corresponding author

Correspondence to Justina M. Burns.

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Burns, J.M., Cooper, W.J., Ferry, J.L. et al. Methods for reactive oxygen species (ROS) detection in aqueous environments. Aquat Sci 74, 683–734 (2012). https://doi.org/10.1007/s00027-012-0251-x

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  • DOI: https://doi.org/10.1007/s00027-012-0251-x

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