Wuhan University Journal of Natural Sciences

, Volume 9, Issue 1, pp 99–101

Synthesis and crystal structure of new supramolecular adducts of [PtCl6]2− with cucurbit [7] uril: [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O

Authors

  • Yan Kun
    • College of Chemistry and Molecular SciencesWuhan University
  • Huang Zi-xiang
    • Fujian Institute of Research on the Structure of Matter, CAS
  • Liu Si-min
    • College of Chemistry and Molecular SciencesWuhan University
  • Liang Feng
    • College of Chemistry and Molecular SciencesWuhan University
  • Wu Cheng-tai
    • College of Chemistry and Molecular SciencesWuhan University
Article

DOI: 10.1007/BF02912727

Cite this article as:
Kun, Y., Zi-xiang, H., Si-min, L. et al. Wuhan Univ. J. Nat. Sci. (2004) 9: 99. doi:10.1007/BF02912727

Abstract

A novel supramolecular adduct [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O (1) was synthesized by mixing [PtCl6]2− and cucurbit [7] uril in solution of hydrochloric acid. The crystal structure was determined by single crystal X-ray diffraction analysis. The crystal belongs to orthorhombic system and space group F dd2 with cell dimensions:a=4. 705 33 (5) nm,b=7. 153 80 (6) nm,c=1. 894 61 (2) nm,Z=16,V=63, 7744 (11) nm3,Dc=1.534 g/cm3, μ=3. 007 mm−1,F(000)=29 120,R1=0.070 7,wR2=0. 169 2. In crystal, the cucurb [7] uril molecules from two zig-zag chains.

Key words

supramolecular adductplatinichloridecucurbiturilcrystal structure

CLC number

O 614.82+6O 641. 4
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Copyright information

© Springer 2004