A principle to correlate extreme values of excess thermodynamic functions with partial molar quantities
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Excess thermodynamic properties are widely used quantitatively for fluids. It was found that at constant temperature and pressure a molar excess quantity of a mutually miscible binary mixture at the extreme points equals the excess partial molar quantities of the two components, i.e.F E 1=F E 2=F E m, forming a triple cross point. The relationship is hold for properties such as enthalpy, entropy, Gibbs free energy, and volume, and is applicable for excess functions with multi extreme points. Solutions at extreme points can be referred to as special mixtures. Particularly for a special mixture of Gibbs free energy, activity coefficients of the two components are identical.
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- A principle to correlate extreme values of excess thermodynamic functions with partial molar quantities
Science in China Series B: Chemistry
Volume 44, Issue 3 , pp 315-319
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- excess properties
- Gibbs energy
- activity coefficient
- triple cross point
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