Proceedings of the Indian Academy of Sciences - Chemical Sciences

, Volume 92, Issue 4, pp 449–456

Crystallographic study of push-pull ethylenes

Authors

  • D. Adhikesavalu
    • Department of Organic ChemistryIndian Institute of Science
  • Nirupa U. Kamath
    • Department of Organic ChemistryIndian Institute of Science
  • K. Venkatesan
    • Department of Organic ChemistryIndian Institute of Science
Crystallography

DOI: 10.1007/BF02839148

Cite this article as:
Adhikesavalu, D., Kamath, N.U. & Venkatesan, K. Proc. Indian Acad. Sci. (Chem. Sci.) (1983) 92: 449. doi:10.1007/BF02839148
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Abstract

From structural data of several crystal structure analyses of push-pull ethylenes it is found that C=C bond lengths in this class of molecules are significantly longer than the value for this bond in ethylene. With powerful donors and acceptors such as -NMe2 and -COOMe groups respectively, the C=C bond length is as long as 1.460 å. Correlations are observed between (i) C=C bond lengths and the twist angles about the C=C bond and (ii) C=C bond lengths and the torsional barrier measured by thednmr technique.

Keywords

X-ray structure analysispush-pull ethylenesC=C bond lengthsrotational barriers
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© Printed in India 1983