Journal of Chemical Sciences

, Volume 118, Issue 1, pp 117–126

Syntheses, structure and intercalation properties of low-dimensional phenylarsonates, A(HO3AsC6H5)(H2O3AsC6H5) (A = Tl, Na, K and Rb)

  • Bonthu Krishna Kishore Reddy
  • K. Prabhakara Rao
  • K. Vidyasagar
Article

DOI: 10.1007/BF02708773

Cite this article as:
Reddy, B.K.K., Rao, K.P. & Vidyasagar, K. J Chem Sci (2006) 118: 117. doi:10.1007/BF02708773

Abstract

Four new low-dimensional phenylarsonates, A(HO3AsC6H5)(H2O3AsC6H5) (A = Tl(1), Na(2), K(3) and Rb(4)), have been synthesized and characterized by X-ray diffraction, spectroscopic and thermal studies. They crystallize in triclinic unit cells and have approximately planar arrangement of A+ ions, coordinated to oxygen atoms of phenylarsonates, on both sides. Structure of thallium phenylarsonate as determined by single crystal X-ray diffraction, is one-dimensional, whereas those of alkalimetal analogues are two-dimensional. Successful intercalation reactions of compounds1 and2 with primaryn-alkyl amines have been demonstrated.

Keywords

Phenylarsonatesorganic-inorganic hybrid compositesX-ray diffractionlow-zimensional compoundsintercalation

Copyright information

© Indian Academy of Sciences 2006

Authors and Affiliations

  • Bonthu Krishna Kishore Reddy
    • 1
  • K. Prabhakara Rao
    • 1
  • K. Vidyasagar
    • 1
  1. 1.Department of ChemistryIndian Institute of Technology MadrasChennai