Journal of Chemical Sciences

, Volume 118, Issue 1, pp 47–55

Design and fabrication of an automated temperature programmed reaction system to evaluate 3-way catalysts Ce1−x−y,(La/Y)xPtyO2−δ

  • Arup Gayen
  • Tinku Baidya
  • G. S. Ramesh
  • R. Srihari
  • M. S. Hegde
Article

DOI: 10.1007/BF02708765

Cite this article as:
Gayen, A., Baidya, T., Ramesh, G.S. et al. J Chem Sci (2006) 118: 47. doi:10.1007/BF02708765

Abstract

A completely automated temperature-programmed reaction (TPR) system for carrying out gas-solid catalytic reactions under atmospheric flow conditions is fabricated to study CO and hydrocarbon oxidation, and NO reduction. The system consists of an all-stainless steel UHV system, quadrupole mass spectrometer SX200 (VG Scientific), a tubular furnace and micro-reactor, a temperature controller, a versatile gas handling system, and a data acquisition and analysis system. The performance of the system has been tested under standard experimental conditions for CO oxidation over well-characterized Ce1−−x−y Ptx(La/Y)yO2-δ catalysts. Testing of 3-way catalysis with CO, NO and C2H2 to convert to CO2, N2 and H2O is done with this catalyst which shows complete removal of pollutants below 325°C. Fixed oxide-ion defects in Pt substituted Ce1−y(La/Y)yO2−y/2 show higher catalytic activity than Pt ion-substituted CeO2.

Keywords

Automatic TPRceria, three way catalysis

Copyright information

© Indian Academy of Sciences 2006

Authors and Affiliations

  • Arup Gayen
    • 1
  • Tinku Baidya
    • 1
  • G. S. Ramesh
    • 2
  • R. Srihari
    • 1
  • M. S. Hegde
    • 1
  1. 1.Solid State and Structural Chemistry UnitIndian Institute of ScienceBangalore
  2. 2.Techno Science InstrumentsBangalore