, Volume 63, Issue 2, pp 245–249

Neutron scattering study of combustion-synthesized Ce1−xCuxO2−x

  • Keka R. Chakraborty
  • P. S. R. Krishna
  • M. S. Hegde

DOI: 10.1007/BF02704980

Cite this article as:
Chakraborty, K.R., Krishna, P.S.R. & Hegde, M.S. Pramana - J Phys (2004) 63: 245. doi:10.1007/BF02704980


Powder neutron diffraction and Hi-Q neutron diffraction data have been recorded and analysed in order to obtain the local and long range order of Cu in Cudoped CeO2 with three doping levels of Cu. Rietveld method and MCGR techniques of data analysis for the two types of data reveal that the Cu ion is in the 2+ oxidation state and has a vacancy in its first coordination shell. These deductions from the data analysis fit well with the mechanism of catalysis we propose.


Combustion synthesis neutron diffraction 


81.20.Ka 61.12.Ld 

Copyright information

© Indian Academy of Science 2004

Authors and Affiliations

  • Keka R. Chakraborty
    • 1
  • P. S. R. Krishna
    • 1
  • M. S. Hegde
    • 2
  1. 1.Solid State Physics DivisionBhabha Atomic Research CentreMumbaiIndia
  2. 2.Solid State and Structural Chemistry UnitIndian Institute of ScienceBangaloreIndia

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