Zirconium(IV) catalysis in perborate oxidation of iodide Authors
Received: 02 January 1995 Accepted: 08 August 1996 DOI:
Cite this article as: Karunakaran, C. & Muthukumaran, B. React Kinet Catal Lett (1997) 60: 387. doi:10.1007/BF02475703 Abstract
Zirconium(IV) catalyzes perborate oxidation of iodide ion. In acidic solution the oxidation is zero order with respect to perborate, first order with respect to Zr(IV), independent of [H
+] and exhibits Michaelis-Menten dependence on [I −]. Mechanistic pathway of the catalysis is discussed and a rate equation is derived. Keywords Perborate iodide zirconium(IV) catalysis oxidation References
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