Journal of Radioanalytical and Nuclear Chemistry

, Volume 230, Issue 1, pp 91–95

Carbonate radical induced polymerisation of pyrrole: A steady state and flash photolysis study

  • Amit Bhattacharya
  • De Amitabha
  • P. C. Mandal
Article

DOI: 10.1007/BF02387452

Cite this article as:
Bhattacharya, A., De Amitabha & Mandal, P.C. J Radioanal Nucl Chem (1998) 230: 91. doi:10.1007/BF02387452

Abstract

Conventionally polymerisation of pyrrole is carried out either by chemical or electrochemical oxidation. In the present study polymerisation of pyrrole was carried out in a novel way in order to investigate the kinetics of the reactions involved. Carbonate radical (CO3) generated either radiolytically or photolytically from a sodium carbonate solution, was employed as the oxidant for the polymerisation reaction Flash photolysis and steady state ψ-radiolysis of pyrrole solution containing sodium carbonate was used for generating different intermediate and stable polymeric species. The kinetics of the formation and decay of different intermediate species were studied using UV-VIS spectrophotometry and the disappearances of the monomer was ascertained using HPLC. After analysing the species and steps involved a plausible mechanism for the polymerisation of pyrrole is suggested.

Copyright information

© Akadémiai Kiadó 1998

Authors and Affiliations

  • Amit Bhattacharya
    • 1
  • De Amitabha
    • 1
  • P. C. Mandal
    • 1
  1. 1.Nuclear Chemistry DivisionSaha Institute of Nuclear PhysicsCalcuttaIndia