Communications in Mathematical Physics

, Volume 147, Issue 3, pp 527–548

Error bound for the Hartree-Fock energy of atoms and molecules

  • Volker Bach
Article

DOI: 10.1007/BF02097241

Cite this article as:
Bach, V. Commun.Math. Phys. (1992) 147: 527. doi:10.1007/BF02097241

Abstract

We estimate the error of the Hartree-Fock energy of atoms and molecules in terms of the one-particle density matrix corresponding to the exact ground state. As an application we show this error to be of orderO(Z5/3−δ) for any δ<2/21 as the total nuclear chargeZ becomes large.

Copyright information

© Springer-Verlag 1992

Authors and Affiliations

  • Volker Bach
    • 1
  1. 1.Institut für Theoretische PhysikETH HönggerbergZürichSwitzerland

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