Abstract
The crystal and molecular structure of the title compound, C21H11N6S4Au, is reported. The crystals are triclinic:P¯1,Z=2,a=7.739(1),b=8.415(1),c=17.815(1) Å,a=101.31(1),β=86.20(1), γ=98.17(1)°. The structure was solved by the heavy-atom method, and refined by full-matrix least squares toR=0.046. Both the Au(mnt) −2 and NMP+ ions are planar, and form a kind of mixed stack alonga, with slightly alternating NMP+-Au(mnt) −2 distances of 3.46(8) and 3.59(5) Å.
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Kuppusamy, P., Venkatalakshmi, N. & Manoharan, P.T. Crystal and molecular structure ofN-methylphenazinium bis(maleonitriledithiolato)gold(III), [NMP]+[Au(mnt)2]− . Journal of Crystallographic and Spectroscopic Research 15, 629–641 (1985). https://doi.org/10.1007/BF01164776
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DOI: https://doi.org/10.1007/BF01164776