Effect of the nature of the polymeric carrier on the catalytic activity of palladium-polyheteroarylene catalysts in hydrogenation reactions

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Conclusions

The activity of palladium-polyheteroarylene catalysts is a function of the electron affinity of the polymer carriers and is determined by the proportion of the Pdδ+ form, formed due to the partial transfer of the electron density from the palladium to the electronic system of the polymer to a significant degree.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2153–2158, October, 1987.