Skip to main content
SpringerLink
Log in

Solubility of sodium tetraphenylborate in solutions of NaCl, Na2NO3, Na2SO4, NaCl+MgCl2 at 25°

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The solubility of sodium tetraphenyiborate (TPB) in solutions of NaCl, NaNO3, Na2SO4 and NaCl+MgCl2 was studied at 25°C.

  2. 2.

    The solubility of sodium TPB drops to zero with increasing concentration of the salting out agent in solution, and 1 g-eq of sodium TPB is isolated per 1.5 g-eq of the added Na salt.

  3. 3.

    The optimum initial concentration of sodium TPB, recommended for the isolation of the salt from aqueous solution and for its purification, is equal to 8%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. Wittig and P. Raff, Liebigs. Ann. Chem.,573, 195 (1951).

    Google Scholar 

  2. Heyl and Co., French Patent No. 1043726, February 10, 1953.

  3. Heyl and Co., British Patent No. 705719, March 17, 1954; Chem. Abstrs.,48, 9279a (1954).

    Google Scholar 

  4. A. F. Ievin'sh and E. Yu. Gudrinietse, Zh. Analit. Khimii,9, 270 (1954).

    Google Scholar 

  5. G. Wittig and P. Raff, US Patent No. 2853525, September 23, 1958; Chem. Abstrs.,53, 4211f (1959).

    Google Scholar 

  6. L. Sporek and A. F. Williams, Analyst,80, 347 (1955).

    Google Scholar 

  7. W. Geilmann and W. Gebauhr, Z. Analyt. Chem.,139, 161 (1953).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. P. Kozitskii

Authors
  1. V. P. Kozitskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 12–14, January, 1971.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kozitskii, V.P. Solubility of sodium tetraphenylborate in solutions of NaCl, Na2NO3, Na2SO4, NaCl+MgCl2 at 25°. Russ Chem Bull 21, 10–12 (1972). https://doi.org/10.1007/BF00855645

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00855645

Keywords

Search

Navigation