Organic and Biological Chemistry

Bulletin of the Academy of Sciences of the USSR, Division of chemical science

, Volume 21, Issue 5, pp 1082-1084

Anodic fluorination of benzene

  • I. N. RozhkovAffiliated withInstitute of Heteroorganic Compounds, Academy of Sciences of the USSR
  • , A. V. BukhtiarovAffiliated withInstitute of Heteroorganic Compounds, Academy of Sciences of the USSR
  • , I. L. KnunyantsAffiliated withInstitute of Heteroorganic Compounds, Academy of Sciences of the USSR

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Conclusions

  1. 1.

    A study was made of the possibility of fluorination at high values of the anode potential.

     
  2. 2.

    Benzene under these conditions is fluorinated to fluorobenzene and difluorobenzene. Fluorobenzene forms difluorobenzene, and further fluorination fails to occur.